By I.M. Kolthoff
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CHAPTER THREE THE ION ACTIVITY THEORY AND ITS APPLICATION TO ACID-BASE EQUILIBRIA 1. Historical review. Classification of electrolytes. of GROTTHUS concerning the elecconductivity of solutions proposed that the positive and negative parts of the electrolyte molecules were transferred from As early as 4805 the theory trical molecule to molecule by a chain mechanism. portions must have an independent existence Consequently these for at least a short time during the electrolysis. These dynamic considerations led R.
B) Buffer capacity of Equation (48) tells a solution of a weak acid and its salt. weak acid with one us that in a mixture of a of its salts (54) THE REACTION OF ACIDS, BASES, AND SALTS We may set [A""] equal to the total salt concentration C l a, 27 so that - (55) where CHA is the concentration of acid. Since the quantity base B added to neutralize the acid forms salt, then [A~] = - _ [B]. If the initial acid the quantity c [BJ. concentration were of [B] base, Hence from equation s then, after addition of c, we (48) v A KT..
M. Noyes, and K. G. Falk: J. Gen. , S, 291 (1921). 8 P. A. Levene and H. S. Simms: J. Biol. , 55, 801 (1923). * W. R. Atkin: Proc. Leeds Phil. Lit. , 1, 165 (1927); Chemical Abstracts, 21, 2210 (1927). 02 ill |wgls3w| ijjljli g a a a'i^ ? 9 OOOO O O " OOOOOOOOOO 00 00 00 1C 00 ^O iO id iO fcC o o o o o XXXXX O